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Words near each other
・ Cobalt(II) chloride
・ Cobalt(II) cyanide
・ Cobalt(II) fluoride
・ Cobalt(II) formate
・ Cobalt(II) hydroxide
・ Cobalt(II) iodide
・ Cobalt(II) naphthenate
・ Cobalt(II) nitrate
・ Cobalt(II) oxalate
・ Cobalt(II) oxide
・ Cobalt(II) phosphide
・ Cobalt(II) selenide
・ Cobalt(II) sulfate
・ Cobalt(II) thiocyanate
・ Cobalt(II,III) oxide
Cobalt(III) fluoride
・ Cobalt(III) nitrate
・ Cobalt(III) oxide
・ Cobalt, Idaho
・ Cobalt, Missouri
・ Cobalt, Ontario
・ Cobalt-59 nuclear magnetic resonance
・ Cobalt-60
・ Cobalt-60 (disambiguation)
・ Cobalt-chrome
・ Cobalt-factor II C20-methyltransferase
・ Cobalt-mediated radical polymerization
・ Cobalt-precorrin 5A hydrolase
・ Cobalt-precorrin-5B (C1)-methyltransferase
・ Cobalt-precorrin-7 (C15)-methyltransferase (decarboxylating)


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Cobalt(III) fluoride : ウィキペディア英語版
Cobalt(III) fluoride

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Cobalt(III) fluoride is the inorganic compound with the formula CoF3. This highly reactive, hygroscopic brown solid is used to synthesize organofluorine compounds.〔Coe, P. L. "Cobalt(III) Fluoride" in Encyclopedia of Reagents for Organic Synthesis (Ed: L. Paquette) 2004, J. Wiley & Sons, New York. .〕 CoF3 is a powerful fluorinating agent that leaves CoF2 as the byproduct.
==Preparation==
CoF3 is prepared in the laboratory by treating CoCl2 with fluorine at 250 °C:〔Priest, H. F. "Anhydrous Metal Fluorides" Inorganic Syntheses McGraw-Hill: New York, 1950; Vol. 3, pages 171-183. 〕
:CoCl2 + 3/2 F2 → CoF3 + Cl2
This conversion is a redox reaction: Co2+ and Cl are oxidized to Co3+ and Cl2, respectively, while F2 is reduced to F. Cobalt(II) oxide (CoO) and cobalt(II) fluoride (CoF2) can also be converted to cobalt(III) fluoride using fluorine.

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